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61.
62.
Understanding interactions between functionalized gold nanoparticles (NPs) and lipid bilayers is essential for biomedical applications. Experiments have shown that NPs that are stable in solution can assemble into clusters when adsorbed to a lipid bilayer, suggesting that bilayer-mediated interactions facilitate assembly. In this work, we use coarse-grained molecular dynamics simulations to study bilayer-mediated interactions between NPs adsorbed to single- and multicomponent lipid bilayers. We perform unbiased simulations and umbrella sampling calculations using an implicit solvent force field to determine the thermodynamic contributions to assembly. We show that bilayer-mediated interactions drive the assembly of NPs into linear aggregates on liquid-disordered bilayers, which we attribute to a reduction in bilayer curvature. Similar bilayer-mediated interactions induce the alignment of NP clusters with phase boundaries in phase-separated bilayers. Together, these simulation results provide new physical insight into the balance of forces that dictate the assembly of charged NPs at multicomponent lipid bilayer interfaces. 相似文献
63.
The clean and effective utilization of titanium-bearing minerals has challenged the titanium industry all over the world. In order to realize the high-efficiency, clean, and high value-added comprehensive utilization of ilmenite concentrate, a novel process has been proposed in this study by reducing and carbonitriding ilmenite with the CH4-N2-H2 gas mixture at low temperature. Carbonitride performance and mechanism have been investigated experimentally and theoretically. The obtained results showed that the reaction process could be divided into three stages: formation of metallic iron, reduction of titanium oxide to titanium suboxides, and formation of Ti(C, O, N). The metallic iron congregated at the first two stages, but dispersed once the Ti(C, O, N) formed. The effects of both reaction temperature and preoxidation treatment on the reaction have been studied as well. It was found that the increase of temperature was conducive to the formation of Ti(C,O), and the ilmenite could be reduced completely to Ti(C,O) at 1170°C for 8 hours. The preoxidation treatment could improve the kinetics of reduction. At 1170°C, the introduction of N2 could apparently increase the reduction rate, with the complete reduction time decreasing from 8 hours in CH4-H2 gas mixture to 3 hours in CH4-N2-H2 gas mixture. The proposed novel process has been assessed and it showed many potential advantages and feasibility. 相似文献
64.
Avanish Bharati Prakhyat Hejmady Tom Van der Donck Jin Won Seo Ruth Cardinaels Paula Moldenaers 《应用聚合物科学杂志》2020,137(9):48433
An approach to induce conductivity in immiscible polystyrene/polypropylene (PS/PP) blends is described using a percolated conducting polyaniline/polyamide (PANI/PA) filler combined with a polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene-graft-maleic anhydride compatibilizer. The approach is based on the ability of the compatibilizer to concomitantly stabilize the cocontinuous morphology and to improve the state of dispersion of the PANI/PA filler. Selective localization of PANI/PA in the PS phase with improved filler dispersion is achieved with the optimal master batch (MB) preparation technique followed by its optimized sequence addition to the blend components. This results in an increase in the dc conductivity by six decades as compared with that of the neat compatibilized blend at an effective 4.8-wt % PANI concentration. An investigation of the effect of functionality and concentration of the filler and the compatibilizer on the filler connectivity in the blend is performed. The prevailing specific interactions are analyzed by Fourier transform infrared spectroscopy and thermogravimetric analysis of the MBs. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48433. 相似文献
65.
Artworks based on Xuan paper or silk and painted by organic or inorganic pigments are highly responsive to light due to their materials and manufacturing technologies. They belong to the highest level of light responsive exhibits stipulated by International Commission on Illumination (CIE) and are vulnerable to fading and discoloration caused by radiation from light sources. The choice of light sources is the key of protection for artworks. It is indispensible and urgent to choose the lowest damage light sources according to the material characteristics of artworks. In this article, long-term irradiation of typical light sources on various substrates and pigments was used as experimental method, and CIE DE2000 color difference formula was used as the evaluation index. The laws of the influence of different light sources on the color change of various materials were obtained, and the relative damage coefficients of light sources were calculated. Finally, eight kinds of light sources suitable for illuminating responsive artworks with typical material combinations were proposed. However, there are some limitations in the study, because the ancient Chinese Xuan paper and silk used as experimental objects in the experiment are yellowish. Thus, the models derived in this article are not suitable for choosing reasonable display light sources for other works of art. However, suitable light sources for different materials could be obtained by the calculation method used in this article. 相似文献
66.
Khanh Dang Douglas Spearot 《JOM Journal of the Minerals, Metals and Materials Society》2018,70(7):1094-1099
The effect of pressure applied normal to the {111} slip plane on the Peierls stress in Al is studied via atomistic simulations. Edge, screw, 30°, and 60° straight dislocations are created using the Volterra displacement fields for isotropic elasticity. For each dislocation character angle, the Peierls stress is calculated based on the change in the internal energy, which is an invariant measure of the dislocation driving force. It is found that the Peierls stress for dislocations under zero pressure is in general agreement with previous results. For screw and 60° dislocations, the Peierls stress versus pressure relationship has maximum values associated with stacking fault widths that are multiples of the Peierls period. For the edge dislocation, the Peierls stress decreases with increasing pressure from tension to compression. Compared with the Mendelev potential, the Peierls stress calculated from the Mishin potential is more sensitive to changes in pressure. 相似文献
67.
Analysis of arbitrarily shaped planar cracks in three-dimensional isotropic hygrothermoelastic media
In the present article, a planar crack of arbitrary shape embedded in three-dimensional isotropic hygrothermoelastic media is investigated. Based on the general solutions and Hankel transform technique, the fundamental solutions for unit-point and extended displacement discontinuities (EDD; including the displacement discontinuities, moisture concentration discontinuity, and the temperature discontinuity) are derived. The EDD boundary integral equations for an arbitrarily shaped, planar crack in the hygrothermoelastic medium are established in terms of the EDD. Utilizing the boundary integral equation method, the singularities of near-crack front fields are analyzed, and the stress, moisture flux, and heat flux intensity factors are all derived in terms of the EDD. As a special case, the analytical solution for a penny-shaped crack under uniform combined loadings is presented. The EDD boundary element method is proposed for numerical simulation. The numerical result for a penny-shaped crack subjected to uniform mechanical–moisture–thermal loading is compared with the analytical solution to verify the correctness of the proposed method. Two coplanar elliptical cracks subjected to combined loadings are simulated as an application, and the influences of applied loadings and the ellipticity ratio are discussed. 相似文献
68.
69.
Yichao Gong Zhong Chen Mao Yang Hailiang Wang Chen Dang Wanxia Huang Tiecheng Lu 《Ceramics International》2018,44(14):16209-16213
Li4SiO4 has been widely studied as attractive tritium breeding materials due to its innate merits. Considering the potential advantages of nanostructure in tritium breeding materials, a distinctive process was developed to obtain nanostructured Li4SiO4 pebbles. In brief, ultrafine precursor powders were synthesized by solvothermal method without using surfactants, and then indirect wet method was adopted to generate the green spheres with homogeneous microstructure. After that, the suitable sintering conditions were defined by studying the effects of sintering parameters on the grain size evolution, and nanostructured Ti-doped Li4SiO4 pebbles were first obtained by two-step sintering method. This study will be expected to provide references for fabricating other Li-based tritium breeding materials. 相似文献
70.
Hui Huang Mingwei Hao Yilong Song Song Dang Xiaoting Liu Qingfeng Dong 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(6)
Perovskite structured CsPbX3 (X = Cl, Br, or I) quantum dots (QDs) have attracted considerable interest in the past few years due to their excellent optoelectronic properties. Surface passivation is one of the main pathways to optimize the optoelectrical performance of perovskite QDs, in which the amino group plays an important role for the corresponding interaction between lead and halide. In this work, it is found that ammonia gas could dramatically increase photoluminescence of purified QDs and effectively passivate surface defects of perovskite QDs introduced during purification, which is a reversible process. This phenomenon makes perovskite QDs a kind of ideal candidate for detection of ammonia gas at room temperature. This QD film sensor displays specific recognition behavior toward ammonia gas due to its significant fluorescence enhancement, while depressed luminescence in case of other gases. The sensor, in turn‐on mode, shows a wide detection range from 25 to 350 ppm with a limit of detection as low as 8.85 ppm. Meanwhile, a fast response time of ≈10 s is achieved, and the recovery time is ≈30 s. The fully reversible, high sensitivity and selectivity characteristics make CsPbBr3 QDs ideal active materials for room‐temperature ammonia sensing. 相似文献